| ALGERIA |
| Youcef Reguigui | 2011 | 2021 |
| Azzedine Lagab | 2007 | 2021 |
| ARGENTINA |
| Juan Jose Haedo | 2007 | 2012 |
| Maximiliano Ariel Richeze Araquistain | 2006 | 2022 |
| Guillermo Ruben Bongiorno | 2005 | 2009 |
| Matias Medici | 2003 | 2012 |
| Daniel Ricardo Diaz | 2009 | 2015 |
| AUSTRALIA |
| Robbie McEwen | 1995 | 2011 |
| Michael Matthews | 2009 | 2022 |
| Cadel Evans | 2001 | 2015 |
| Phil Anderson | 1980 | 1994 |
| Simon Gerrans | 2004 | 2018 |
| Caleb Ewan | 2015 | 2022 |
| AUSTRIA |
| Max Bulla | 1931 | 1936 |
| Georg Totschnig | 1990 | 2005 |
| Bernhard Eisel | 2002 | 2019 |
| Helmut Wechselberger | 1981 | 1988 |
| AZERBAIJAN |
| Kirill Pozdnyakov | 2011 | 2013 |
| BELARUS |
| Yauheni Hutarovich | 2003 | 2016 |
| Vasil Kiryienka | 1999 | 2019 |
| Alexandre Usov | 2002 | 2010 |
| Aliaksandr Kuchynski | 2001 | 2014 |
| Kanstantsin Sivtsov | 2002 | 2018 |
| BELGIUM |
| Eddy Merckx | 1965 | 1977 |
| Roger De Vlaeminck | 1969 | 1984 |
| Freddy Maertens | 1973 | 1981 |
| Rik Van Looy | 1954 | 1969 |
| Philippe Gilbert | 2003 | 2022 |
| BRAZIL |
| Murilo Antonio Fischer | 2004 | 2016 |
| Cassio Freitas de Paiva | 1989 | 2001 |
| Mauro Ribeiro | 1988 | 1991 |
| Luciano Pagliarini Mendonca | 2003 | 2010 |
| Rafael Andriato | 2010 | 2022 |
| BULGARIA |
| Ivailo Gabrovski | 2001 | 2012 |
| Danail Andonov Petrov | 2002 | 2013 |
| Svetoslav Tchanliev Kirilov | 1997 | 2011 |
| Vladimir Koev | 2001 | 2012 |
| CANADA |
| Ryder Hesjedal | 2005 | 2016 |
| Michael Woods | 2014 | 2022 |
| Steve Bauer | 1984 | 1996 |
| Svein Tuft | 2001 | 2018 |
| Brian Walton | 1990 | 2000 |
| CHILE |
| Carlos-Ivan Oyarzun Guinez | 2010 | 2014 |
| Marco Arriagada | 1999 | 2011 |
| CHINA |
| Xianjing Lyu | 2019 | 2019 |
| COLOMBIA |
| Nairo Alexander Quintana Rojas | 2010 | 2022 |
| Rigoberto Uran Uran | 2007 | 2022 |
| Egan Arley Bernal Gomez | 2017 | 2021 |
| Luis Alberto Herrera Herrera | 1984 | 1992 |
| Jhoan Esteban Chaves Rubio | 2011 | 2022 |
| Fernando Gaviria Rendon | 2016 | 2022 |
| Santiago Botero Echeverry | 1999 | 2009 |
| COSTA RICA |
| Andrey Amador Bikkazakova | 2011 | 2022 |
| CROATIA |
| Radoslav Rogina | 1999 | 2015 |
| Robert Kiserlovski | 2006 | 2018 |
| Vladimir Miholjevic | 1998 | 2012 |
| Matija Kvasina | 2004 | 2015 |
| Kristijan Durasek | 2007 | 2018 |
| CUBA |
| Arnold Alcolea Nunez | 2001 | 2014 |
| CZECHIA |
| Jan Svorada | 1995 | 2005 |
| Roman Kreuziger | 2007 | 2021 |
| Zdenek Stybar | 2009 | 2022 |
| Ondrej Sosenka | 1998 | 2006 |
| Jan Barta | 2009 | 2021 |
| CZECHOSLOVAKIA |
| Jan Svorada | 1990 | 1992 |
| Roman Kreuziger (1965) | 1990 | 1991 |
| Milan Jurco | 1982 | 1988 |
| DENMARK |
| Rolf Sörensen | 1986 | 2000 |
| Jakob Fuglsang | 2008 | 2022 |
| Bjarne Riis | 1988 | 1998 |
| Kim Andersen | 1980 | 1991 |
| Matti Breschel | 2004 | 2019 |
| Magnus Cort Nielsen | 2013 | 2022 |
| ECUADOR |
| Richard Antonio Carapaz Montenegro | 2013 | 2022 |
| Jhonatan Manuel Narvaez Prado | 2017 | 2022 |
| Byron Patrico Guama De La Cruz | 2007 | 2021 |
| ERITREA |
| Daniel Teklehaimanot Girmazion | 2009 | 2019 |
| Biniam Girmay Hailu | 2020 | 2022 |
| Natnael Tesfatsion | 2020 | 2022 |
| Natnael Teweldemedhin Berhane | 2009 | 2021 |
| Henok Mulueberhan | 2020 | 2022 |
| ESTONIA |
| Jaan Kirsipuu | 1993 | 2011 |
| Janek Tombak | 1998 | 2009 |
| Rein Taaramäe | 2007 | 2022 |
| Erki Pütsep | 2002 | 2012 |
| Lauri Aus | 1997 | 2003 |
| ETHIOPIA |
| Tsgabu Grmay Gebremariam | 2011 | 2022 |
| FINLAND |
| Jussi Veikkanen | 2002 | 2015 |
| Joona Laukka | 1994 | 2001 |
| Miika Hietanen | 1993 | 1999 |
| FRANCE |
| Bernard Hinault | 1975 | 1986 |
| Laurent Jalabert | 1989 | 2002 |
| Jacques Anquetil | 1954 | 1969 |
| Raymond Poulidor | 1960 | 1976 |
| Louison Bobet | 1948 | 1959 |
| Arnaud Démare | 2012 | 2022 |
| GERMAN DEMOCRATIC REPUBLIC |
| Olaf Ludwig | 1980 | 1990 |
| Jens Heppner | 1986 | 1987 |
| Uwe Raab | 1990 | 1990 |
| Uwe Ampler | 1985 | 1990 |
| Mario Kummer | 1984 | 1987 |
| GERMANY |
| Erik Zabel | 1993 | 2008 |
| André Greipel | 2006 | 2021 |
| Jan Ullrich | 1993 | 2006 |
| Rudi Altig | 1961 | 1970 |
| John Degenkolb | 2009 | 2022 |
| Marcel Kittel | 2011 | 2018 |
| HONG KONG |
| Kam-Po Wong | 1999 | 2013 |
| HUNGARY |
| Laszlo Bodrogi | 1997 | 2008 |
| Attila Valter | 2019 | 2022 |
| IRAN (ISLAMIC REPUBLIC OF) |
| Hossein Askari | 2004 | 2013 |
| Ghader Mizbani Iranagh | 2002 | 2013 |
| Mahdi Sohrabi | 2005 | 2013 |
| Mirsamad Pourseyedi Golakhor | 2009 | 2019 |
| Hossein Alizadeh | 2010 | 2012 |
| IRELAND |
| Sean Kelly | 1977 | 1994 |
| Stephen Roche | 1981 | 1992 |
| Sam Bennett | 2009 | 2022 |
| Daniel Martin | 2008 | 2021 |
| Seamus Elliott | 1956 | 1965 |
| ITALY |
| Francesco Moser | 1971 | 1987 |
| Gino Bartali | 1935 | 1954 |
| Fausto Coppi | 1939 | 1956 |
| Alfredo Binda | 1925 | 1935 |
| Felice Gimondi | 1965 | 1978 |
| Mario Cipollini | 1989 | 2003 |
| Alessandro Petacchi | 2000 | 2014 |
| JAPAN |
| Yukiya Arashiro | 2006 | 2022 |
| Nariyuki Masuda | 2012 | 2022 |
| Takashi Miyazawa | 2007 | 2012 |
| Yoshiyuki Abe | 1996 | 2006 |
| Taiji Nishitani | 2007 | 2013 |
| KAZAKHSTAN |
| Alexandre Vinokourov | 1997 | 2012 |
| Alexey Lutsenko | 2011 | 2022 |
| Maxim Iglinskiy | 2004 | 2014 |
| Andrey Kashechkin | 2004 | 2013 |
| Alexandr Shefer | 1994 | 2003 |
| KOREA (THE REPUBLIC OF) |
| Hyeong-min Choe | 2010 | 2014 |
| KYRGYZSTAN |
| Eugen Wacker | 2000 | 2014 |
| LATVIA |
| Romans Vainsteins | 1995 | 2004 |
| Piotr Ugrumov | 1993 | 1995 |
| Aleksejs Saramotins | 2004 | 2017 |
| Arvis Piziks | 1990 | 2002 |
| Raivis Belohvosciks | 1999 | 2009 |
| LITHUANIA |
| Raimundas Rumsas | 1992 | 2005 |
| Ramunas Navardauskas | 2007 | 2016 |
| Arturas Kasputis | 1991 | 2002 |
| Tomas Vaitkus | 2003 | 2013 |
| Aidis Kruopis | 2010 | 2018 |
| LUXEMBOURG |
| Nicolas Frantz | 1923 | 1934 |
| Charly Gaul | 1951 | 1962 |
| François Faber | 1907 | 1914 |
| Andy Schleck | 2005 | 2014 |
| Fränk Schleck | 2000 | 2016 |
| MALAYSIA |
| Mohamed Harrif Saleh | 2009 | 2022 |
| MEXICO |
| Raul Alcala Gallegos | 1987 | 1994 |
| Julio Alberto Perez Cuapio | 2000 | 2005 |
| Ignacio Sarabia Diaz | 2009 | 2014 |
| Moises Aldape Chavez | 2005 | 2010 |
| MOLDOVA (THE REPUBLIC OF) |
| Andrei Tchmil | 1993 | 1994 |
| Ruslan Ivanov | 1997 | 2008 |
| MOROCCO |
| Adil Jelloul | 2002 | 2014 |
| NETHERLANDS |
| Joop Zoetemelk | 1969 | 1987 |
| Jan Raas | 1974 | 1984 |
| Gerrie Knetemann | 1971 | 1987 |
| Jan Janssen | 1960 | 1971 |
| Adri van der Poel | 1981 | 1994 |
| NETHERLANDS ANTILLES |
| Marc de Maar | 2011 | 2015 |
| NEW ZEALAND |
| Gregory Henderson | 2000 | 2016 |
| Julian Dean | 1998 | 2012 |
| Jesse Sergent | 2009 | 2016 |
| George Bennett | 2011 | 2022 |
| Paul Odlin | 2008 | 2013 |
| NORWAY |
| Alexander Kristoff | 2007 | 2022 |
| Thor Hushovd | 2000 | 2014 |
| Edvald Boasson Hagen | 2006 | 2022 |
| Knut Knudsen | 1974 | 1981 |
| Kurt-Asle Arvesen | 1997 | 2011 |
| POLAND |
| Michal Kwiatkowski | 2010 | 2022 |
| Rafal Majka | 2010 | 2022 |
| Zenon Jaskula | 1986 | 1997 |
| Tomasz Brozyna | 1990 | 2006 |
| Lech Piasecki | 1985 | 1990 |
| PORTUGAL |
| Rui Alberto Costa Faria | 2009 | 2022 |
| Joaquim Agostinho | 1968 | 1981 |
| Acacio Da Silva Mora | 1983 | 1991 |
| Candido Joaquim Barbosa Venda Moreira | 1994 | 2010 |
| João Pedro Gonçalves Almeida | 2018 | 2022 |
| Antonio Barbosa Alves | 1951 | 1961 |
| ROMANIA |
| Eduard-Michael Grosu | 2012 | 2022 |
| RUSSIAN FEDERATION |
| Denis Menchov | 2000 | 2013 |
| Pavel Tonkov | 1992 | 2004 |
| Serguei Ivanov | 1995 | 2011 |
| Dimitri Konyshev | 1992 | 2004 |
| Evgeni Berzin | 1992 | 1998 |
| RWANDA |
| Moise Mugisha | 2019 | 2022 |
| SLOVAKIA |
| Peter Sagan | 2009 | 2022 |
| Jan Svorada | 1993 | 1994 |
| Peter Velits | 2007 | 2014 |
| SLOVENIA |
| Primoz Roglic | 2014 | 2022 |
| Tadej Pogacar | 2019 | 2022 |
| Simon Spilak | 2009 | 2018 |
| Matej Mohoric | 2013 | 2022 |
| Grega Bole | 2008 | 2022 |
| Luka Mezgec | 2012 | 2019 |
| SOUTH AFRICA |
| Robert Hunter | 1999 | 2013 |
| Daryl Impey | 2009 | 2022 |
| Reinardt Janse van Rensburg | 2009 | 2022 |
| Ryan Gibbons | 2016 | 2022 |
| Jay Robert Thomson | 2009 | 2019 |
| SPAIN |
| Alejandro Valverde Belmonte | 2002 | 2022 |
| Miguel Indurain Larraya | 1985 | 1996 |
| Alberto Contador Velasco | 2003 | 2017 |
| Luis Ocana Pernia | 1968 | 1977 |
| Joaquin Pascual Rodriguez Oliver | 2001 | 2016 |
| Delio Rodriguez Barros | 1940 | 1947 |
| Miguel Poblet Orriols | 1947 | 1961 |
| SWEDEN |
| Tommy Prim | 1978 | 1985 |
| Gösta Pettersson | 1967 | 1974 |
| Bernt Johansson | 1977 | 1981 |
| Magnus Backstedt | 1996 | 2008 |
| Sven-Ake Nilsson | 1977 | 1983 |
| SWITZERLAND |
| Tony Rominger | 1987 | 1997 |
| Fabian Cancellara | 2001 | 2016 |
| Ferdi Kübler | 1941 | 1956 |
| Alex Zülle | 1991 | 2003 |
| Hugo Koblet | 1947 | 1957 |
| THAILAND |
| Sarawut Sirironnachai | 2020 | 2021 |
| TURKEY |
| Mert Mutlu | 2003 | 2011 |
| UKRAINE |
| Andrei Tchmil | 1995 | 1997 |
| Serhiy Honchar | 1997 | 2008 |
| Mikhaylo Khalilov | 1995 | 2009 |
| Sergei Outschakov | 1993 | 1999 |
| Yaroslav Popovych | 2003 | 2016 |
| Yuri Metlushenko | 2002 | 2013 |
| UNITED KINGDOM OF GREAT BRITAIN AND NORTHERN IRELAND |
| Chris Froome | 2008 | 2021 |
| Mark Cavendish | 2007 | 2022 |
| Bradley Wiggins | 2001 | 2015 |
| Geraint Thomas | 2006 | 2022 |
| Robert Millar | 1980 | 1995 |
| UNITED STATES OF AMERICA (THE) |
| Greg Lemond | 1980 | 1994 |
| Levi Leipheimer | 1998 | 2012 |
| Tyler Farrar | 2004 | 2017 |
| Andrew Hampsten | 1985 | 1994 |
| URUGUAY |
| Mauricio Moreira | 2021 | 2021 |
| USSR |
| Andrei Tchmil | 1989 | 1991 |
| Dimitri Konyshev | 1987 | 1991 |
| Djamolidine Abduzhaparov | 1990 | 1991 |
| Piotr Ugrumov | 1984 | 1991 |
| Ivan Ivanov | 1987 | 1991 |
| UZBEKISTAN |
| Djamolidine Abduzhaparov | 1992 | 1997 |
| Sergey Lagutin | 2003 | 2017 |
| Muradjan Halmuratov | 2007 | 2022 |
| Sergey Krushevskiy | 2002 | 2004 |
| VENEZUELA (BOLIVARIAN REPUBLIC OF) |
| Jose Rujano Guillen | 2002 | 2014 |
| Leonardo Sierra Sepulveda | 1990 | 1993 |
| Unai Etxebarria Arana | 1998 | 2007 |
| Yonathan Alejandro Monsalve Pertsinidis | 2009 | 2015 |
| Jackson Jesus Rodriguez Ortiz | 2008 | 2014 |
| YUGOSLAVIA |
| Valter Bonca | 1989 | 1989 |
| ZIMBABWE |
| Timothy Jones | 1998 | 2004 |