Datum: 1966-05-02 | Afstand: 253.00 km | UCI:
| Pos | Coureur | Nat | Ploeg |
|---|---|---|---|
| 1 | Jacques Anquetil | FRA | - |
| 2 | Victor Van Schil | BEL | - |
| 3 | Willy In 't Ven | BEL | - |
| 4 | Walter Godefroot | BEL | - |
| 5 | Willy Planckaert | BEL | - |
| 6 | Michele Dancelli | ITA | - |
| 7 | Willy Bocklant | BEL | - |
| 8 | Eddy Merckx | BEL | - |
| 9 | Jozef Huysmans | BEL | - |
| 10 | Roger Swerts | BEL | - |
| 11 | Joseph Spruyt | BEL | - |
| 12 | Johny Schleck | LUX | - |
| 13 | Willy Monty | BEL | - |
| 14 | Jean-Pierre Genet | FRA | - |
| 15 | Gianni Motta | ITA | - |
| 16 | Guido De Rosso | ITA | - |
| 17 | Felice Gimondi | ITA | - |
| 18 | Rudi Altig | DUI | - |
| 19 | Alan Ramsbottom | GBR | - |
| 20 | Armand Desmet | BEL | - |
| 21 | Pierre Vreys | BEL | - |
| 22 | Roger Milliot | FRA | - |
| 23 | Adriano Durante | ITA | - |
| 24 | Yvo Molenaers | BEL | - |
| 25 | Julien Delocht | BEL | - |
| 26 | Emile Bodart | BEL | - |
| 27 | Marcel Kubacki | BEL | - |
| 28 | Kamiel Vyncke | BEL | - |